Highly Monodispersed PbS Quantum Dots for Outstanding Cascaded-Junction Solar Cells
نویسندگان
چکیده
High-performance cascaded-junction quantum dot solar cells (CJQDSCs) are fabricated from as-prepared highly monodispersed lead sulfide QDs. The cells have a high power conversion of 9.05% and a short-circuit current density of 32.51 mA cm-2. A reliable and effective stratagem for fabricating high-quality lead sulfide quantum dots (QD) is explored through a "monomer" concentration-controlled experiment. Robust QDSC performances with different band gaps are demonstrated from the as-proposed synthesis and processing stratagems. Various potential CJQDSCs can be envisioned from the band edge evolution of the QDs as a function of size and ligands reported here.
منابع مشابه
Effect of PbS Film Thickness on the Performance of Colloidal Quantum Dot Solar Cells
Colloidal quantum dots offer broad tuning of semiconductor band structure via the quantum size effect. In this paper, we present a detailed investigation on the influence of the thickness of colloidal lead sulfide (PbS) nanocrystals (active layer) to the photovoltaic performance of colloidal quantum dot solar cells. The PbS nanocrystals (QDs) were synthesized in a non-coordinating solvent, 1-oc...
متن کاملحساس سازی همزمان سلولهای خورشیدی نقاط کوانتومی متشکل ازفوتوآند نانوبلوری TiO2 با نانوذرات CdS و PbS و بررسی تأثیر نقاط کوانتومی PbS بر عملکرد سلول خورشیدی
In this research, CdS and PbS quantum dots were applied as the light sensitizers in TiO2 based nanostructured solar cells. The PbS quantum dots could absorb a wide range of the sunlight spectrum on earth due to their low bandgap energy. As a result, the cell sensitization is more effective by application of both CdS and PbS quantum dots sensitizers. The TiO2 nanocrystals were synthesized throug...
متن کاملIntroducing nanostructure patterns for performance enhancement in PbS colloidal quantum dot solar cells
With attention to the thin film structure of colloidal quantum dot solar cells, in this paper in order to improvement of active layer absorption of them, we have proposed the use of nanostructure pattern for enhancement of their performance. For this purpose we have presented suitable nano hemisphare patterns in colloidal quantum dot solar cells for light trapping in absorption layer. Then with...
متن کاملHybrid polymer/ZnO solar cells sensitized by PbS quantum dots
Poly[2-methoxy-5-(2-ethylhexyloxy-p-phenylenevinylene)]/ZnO nanorod hybrid solar cells consisting of PbS quantum dots [QDs] prepared by a chemical bath deposition method were fabricated. An optimum coating of the QDs on the ZnO nanorods could strongly improve the performance of the solar cells. A maximum power conversion efficiency of 0.42% was achieved for the PbS QDs' sensitive solar cell coa...
متن کاملSensitized solar cells with colloidal PbS-CdS core-shell quantum dots.
We report on the fabrication of PbS-CdS (core-shell) quantum dot (QD)-sensitized solar cells by direct adsorption of core-shell QDs on mesoporous TiO2 followed by 3-mercaptopropionic acid ligand exchange. PbS-CdS QD-sensitized solar cells show 4 times higher efficiency with respect to solar cells sensitized with PbS QDs. The significantly enhanced mean electron lifetime and electron diffusion l...
متن کامل